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ヘルムホルツの自由エネルギー

ヘルムホルツの自由エネルギーFは、内部エネルギーU,基本温度τ,エントロピーσを用いて、F=U-τσと定義されます。系が熱平衡状態にあるときFは極小となります。
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#ヘルムホルツの自由エネルギー
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